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Efficient degradation of imidacloprid by surface discharge cold plasma: Mechanism of interaction between ROS and molecular structure and evaluation of residual toxicity

文献类型： 外文期刊

作者： Ni, Jia-Bao 1 ; Jia, Xiao-Fang 3 ; Zhang, Jun-Ying 3 ; Ding, Chang-Jiang 4 ; Tian, Wen-Li 1 ; Peng, Wen-Jun 1 ; Zielinska, Sara 5 ; Xiao, Hong-Wei 2 ; Fang, Xiao-Ming 1 ;

作者机构： 1.Chinese Acad Agr Sci, Inst Apicultural Res, State Key Lab Resource Insects, 1 Xiangshan Beigou, Beijing 100093, Peoples R China

2.China Agr Univ, Coll Engn, POB 194,17 Qinghua Donglu, Beijing 100083, Peoples R China

3.Beihang Univ, Sch Phys, Beijing, Peoples R China

4.Inner Mongolia Univ Technol, Coll Sci, Hohhot, Peoples R China

5.Wroclaw Univ Sci & Technol, Fac Mech & Power Engn, Wroclaw, Poland

关键词： Neonicotinoid pesticides; Imidacloprid; Cold plasma; Reactive oxygen species; Formation energy

期刊名称：JOURNAL OF HAZARDOUS MATERIALS （ 影响因子：13.6； 五年影响因子：12.7 ）

ISSN： 0304-3894

年卷期： 2024 年 465 卷

页码：

收录情况： SCI

摘要： Incorrect use of neonicotinoid pesticides poses a serious threat to human and pollinator health, as these substances are commonly present in bee products and even drinking water. To combat this threat, the study developed a new method of degrading the pesticide imidacloprid using surface discharge cold plasma oxidation technology. The study showed that this method achieved a very high efficiency of imidacloprid degradation of 91.4%. The main reactive oxygen species (H2O2, O3, & sdot;OH, O2- , 1O2) effectively participated in the decomposition reaction of imidacloprid. Reactive oxygen species were more sensitive to the structure of the nitroimine group. Density functional theory (DFT) further explored the sites of reactive oxygen species attack on imidacloprid and revealed the process of energy change of attacking imidacloprid. In addition, a degradation pathway for imidacloprid was proposed, mainly involving reactive oxygen species chemisorption, a ring-opening intermediate, and complete cleavage of the nitroimine group structure. Model predictions indicated that acute oral and developmental toxicity were significantly reduced after cold plasma treatment, as confirmed by insect experiments. Animal experiments have shown that plasma treatment reduces imidacloprid damage to mice hippocampal tissue structure and inhibits the reduction of brain-derived neurotrophic factor content, thus revealing the detoxification mechanism of the body.

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