Borate Cross-Linking Chitosan/Graphene Oxide Films: Toward the Simultaneous Enhancement of Gases Barrier and Mechanical Properties
文献类型: 会议论文
第一作者: Ning Yan
作者: Ning Yan 1 ; Filomena Capezzuto 1 ; Giovanna G. Buonocore 1 ; Fabiana Tescione 1 ; Marino Lavorgna 1 ; Hesheng Xia 2 ; Luigi Ambrosio 1 ;
作者机构: 1.Institute of Polymers, Composites and Biomaterials, National Research Council, P. le Fermi, 1-80055 Portici, NA, Italy
2.State Key Laboratory of Polymer Materials Engineering, Polymer Research Institute of Sichuan University, Chengdu 610065, China
关键词: graphene oxide;tensile strength;crosslinked
会议名称: International Conference GT70
主办单位:
页码: 020018-1-020018-4
摘要: Borate adducts, originated from hydrolysis of sodium tetraborate decahydrate (borax), have been used to crosslink chitosan (CS) and graphene oxide (GO) nanosheets for the production of innovative composite sustainable materials. CS/GO film consisting of 10wt% borax and lwt% GO exhibits a significant improvement of both toughness and oxygen barrier properties in comparison to pristine chitosan. In particular the tensile strength increases by about 100% and 150% after thermal annealing of samples at 90°C for 50min whereas the oxygen permeability reduces of about 90% compared to pristine chitosan. The enhancement of both mechanical and barrier properties is ascribed to the formation of a resistant network due to the chemical crosslinking, including borate orthoester bonds and hydroxyl moieties complexes, formed among borate ions, chitosan, and GO nanoplatelets. The crosslinked graphene-based chitosan material with its enhanced mechanical and barrier properties may significantly broad the range of applications of chitosan based-materials which presently are very limited and addressed only to packaging.
分类号: o63-532
- 相关文献
[1]Effects of rice straw incorporation and tillage depth on soil puddlability and mechanical properties during rice growth period. Yao, Shuihong,Teng, Xiaolong,Zhang, Bin.
[2]Physical response of rigid and non-rigid soils to analogues of biological exudates. Peng, X.,Hallett, P. D.,Zhang, B.,Horn, R..
[3]Tensile Strength and Microscopic Adhesion Observation of Dental Composite Restorative Material Manufactured From Sisal Nanofiber as Filler. Dwi Aji Nugroho,Widjijono,Nuryono,Widya Asmara,Aulia Rahmasari,Ensa Dyota. 2020
[4]Preparation of Tetraethylenepentamine Modified Magnetic Graphene Oxide for Adsorption of Dyes from Aqueous Solution. Tang, Xiaosheng,Tang, Xiaosheng,Tang, Xiaosheng,Tang, Ping,Liu, Liangliang,Tang, Ping. 2018
[5]Graphene oxide modulates root growth of Brassica napus L. and regulates ABA and IAA concentration. Cheng, Fan,Liu, Yu-Feng,Xie, Ling-Li,Yuan, Cheng-Fei,Xu, Ben-Bo,Lu, Guang-Yuan,Zhang, Xue-Kun.
[6]Preparation of Carriers Based on ZnO Nanoparticles Decorated on Graphene Oxide (GO) Nanosheets for Efficient Immobilization of Lipase from Candida rugosa. Zhang, Shan,Shi, Jie,Deng, Qianchun,Zheng, Mingming,Wan, Chuyun,Zheng, Chang,Li, Ya,Huang, Fenghong.
[7]Enhanced Performance of Magnetic Graphene Oxide-Immobilized Laccase and Its Application for the Decolorization of Dyes. Chen, Jing,Leng, Juan,Yang, Xiai,Liao, Liping,Liu, Liangliang,Xiao, Aiping.
[8]Solid-phase purification and extraction for the determination of trace neonicotinoid pesticides in tea infusion. Zhang, Minglu,Chen, Hongping,Zhu, Li,Wang, Chuanpi,Ma, Guicen,Liu, Xin,Zhang, Minglu,Chen, Hongping,Zhu, Li,Wang, Chuanpi,Ma, Guicen,Liu, Xin.
[9]Graphene Oxides Decorated with Carnosine as an Adjuvant To Modulate Innate Immune and Improve Adaptive Immunity in Vivo. Meng, Chunchun,Li, Chuanfeng,Chen, Zongyan,Qiu, Xusheng,Ding, Chan,Liu, Guangqing,Zhi, Xiao,Li, Chao,Chen, Di,Cui, Daxiang,Ding, Chan,Liu, Guangqing,Ma, Lijun,Lu, Hongmin.
[10]Ultrasmall Graphene Oxide Supported Gold Nanoparticles as Adjuvants Improve Humoral and Cellular Immunity in Mice. Cao, Yuhua,Ma, Yufei,Zhang, Mengxin,Wang, Haiming,Tu, Xiaolong,Shen, He,Dai, Jianwu,Zhang, Zhijun,Cao, Yuhua,Zhang, Mengxin,Tu, Xiaolong,Shen, He,Wang, Haiming,Guo, Huichen.
[11]One-pot synthesis of magnetic zeolitic imidazolate framework/grapheme oxide composites for the extraction of neonicotinoid insecticides from environmental water samples. Cao, Xiaolin,Jiang, Zejun,Wang, Shanshan,Hong, Sihui,Li, Hui,Shao, Yong,She, Yongxin,Wang, Jing,Jin, Fen,Jin, Maojun. 2017
[12]p-Phenylenediamine Functionalized Magnetic Graphene Oxide for the Removal of Congo Red from Wastewater. Tang, Ping,Si, Shihui,Tang, Ping,Liu, Liangliang,Tang, Xiaosheng,Tang, Xiaosheng. 2016
[13]Enhanced Proliferation and Osteogenic Differentiation of Mesenchymal Stem Cells on Graphene Oxide-Incorporated Electrospun Poly(lactic-co-glycolic acid) Nanofibrous Mats. Luo, Yu,Shen, He,Cao, Yuhua,Huang, Jie,Zhang, Mengxin,Dai, Jianwu,Zhang, Zhijun,Luo, Yu,Shi, Xiangyang,Fang, Yongxiang,Dai, Jianwu,Fang, Yongxiang. 2015
[14]Conjugated cationic polymer-assisted amplified fluorescent biosensor for protein detection via terminal protection of small molecule-linked DNA and graphene oxide. Zhang, Zhen,Xia, Xiaoyang,Xiang, Xia,Huang, Fenghong,Han, Ling.
[15]Graphene-based Biosensors for Biomolecules Detection. Zheng, Qing,Wu, Hao,Wang, Nan,Ding, Kejian,Ma, Yuehui,Guang, Weijun,Yan, Rui,Wang, Junzhong.
[16]Adsorption kinetics, isotherms and thermodynamics of Cr(III) on graphene oxide. Yang, Shuang,Pei, Zhiguo,Li, Chunmei,Lv, Jitao,Xie, Jieli,Wen, Bei,Zhang, Shuzhen,Li, Lingyun.
[17]Adsorption and removal of bisphenol A from aqueous solution by p-phenylenediamine-modified magnetic graphene oxide. Tang, Xiaosheng,Tang, Xiaosheng,Tang, Ping,Liu, Liangliang,Tang, Ping,Si, Shihui. 2017
[18]Graphene oxide: An adsorbent for the extraction and quantification of aflatoxins in peanuts by high-performance liquid chromatography. Yu, Li,Li, Peiwu,Zhang, Qi,Zhang, Wen,Ding, Xiaoxia,Wang, Xiupin,Yu, Li,Zhang, Qi,Zhang, Wen,Ding, Xiaoxia,Wang, Xiupin,Li, Peiwu,Li, Peiwu,Ding, Xiaoxia,Yu, Li,Li, Peiwu,Zhang, Wen,Wang, Xiupin.
[19]Immobilisation of acid pectinase on graphene oxide nanosheets. Liu, Yang,Li, Qiang,Feng, Yuan-Yuan,Ji, Geng-Sheng,Li, Tian-Cheng,Tu, Jie,Gu, Xu-Ding,Li, Qiang.
[20]Preparation of Graphene Oxide and Its Mechanism in Promoting Tomato Roots Growth. Jiao, Jingzhi,Cheng, Fan,Xie, Lingli,Yuan, Chengfei,Xu, Benbo,Zhang, Xuekun,Li, Zhiyang,Zhang, Liming.
作者其他论文 更多>>
-
Measurement of Strain on 3D-Printed Foot Prosthesis Using Fiber Bragg Grating Sensors
作者:Sara Del Chicca;Abdel Rahman Nedal Ibrahim Al Thahabi;Luca Michele Martulli;Gennaro Rollo;Jacopo Romanò;Lorenzo Garavaglia;Andrea Bernasconi;Marino Lavorgna;Andrea Sorrentino;Simone Pittaccio;Emanuele Gruppioni;Paola Saccomandi;Marco Tarabini
关键词:Performance evaluation;Optical fibers;Optical fiber sensors;Fiber gratings;Three-dimensional printing;Strain measurement;Monitoring
-
Electro Fluido Dynamic Techniques To Design Instructive Biomaterials For Tissue Engineering and Drug Delivery
作者:Vincenzo Guarino;Rosaria Altobelli;Valentina Cirillo;Luigi Ambrosio
关键词:physical;biological;fundamental cell-biomaterial
-
Effect of Compatibilization on the Properties of In Situ Microfibrillar Composites based on Polylactic acid and Polypropylene
作者:Maria Oliviero;Giovanna G. Buonocore;Letizia Verdolotti;Marino Lavorgna
关键词:concept;cold stretching;effect
-
Optimization of Protein Cross-linking in Bicomponent Electrospun Scaffolds for Therapeutic Use
作者:Antonio Papa;Vincenzo Guarino;Valentina Cirillo;Olimpia Oliviero;Luigi Ambrosio
关键词:combination;regeneration;design
-
Biomineralized hydroxyapatite nanocrystals/graphene oxide as filler for bone tissue engineering
作者:Maria Grazia Raucci;Daniela Giugliano;Angela Longo;Stefania Zeppetelli;Gianfranco Carotenuto;Luigi Ambrosio
关键词:
-
Effect of surfaces properties on bone differentiation in composite scaffolds
作者:Vincenzo Guarino;Marica Marrese;Francesca Veronesi;Paola Torricelli;Monica Sandri;Anna Tampieri;Milena Fini;Luigi Ambrosio
关键词:
-
Osteogenic differentiation induced by biomineralized gelatin scaffold
作者:Daniela Giugliano;Maria Grazia Raucci;Luigi Ambrosio
关键词:


