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Visible light photocatalytic degradation of pesticides and antibiotics by H3PO4-activated biochar combined with g-C3N4: Effects, mechanism, degradation pathway, and toxicity assessment

文献类型： 外文期刊

作者： Shi, Haojie 1 ; Wang, Wei 1 ; Mao, Liangang 1 ; Zhang, Lan 1 ; Zhu, Lizhen 1 ; Wu, Chi 1 ; Liu, Xingang 1 ;

作者机构： 1.Chinese Acad Agr Sci, State Key Lab Biol Plant Dis & Insect Pests, Inst Plant Protect, Beijing 100193, Peoples R China

关键词： Biochar; Pesticide; Antibiotic; Photodegradation

期刊名称：JOURNAL OF ENVIRONMENTAL MANAGEMENT （ 影响因子：8.4； 五年影响因子：8.6 ）

ISSN： 0301-4797

年卷期： 2025 年 380 卷

页码：

收录情况： SCI

摘要： In recent decades, aquatic environmental pollution resulting from the extensive use of pesticides and antibiotics in the agriculture and livestock industries has become a major concern. In this study, a H3PO4-activated biocharg-C3N4 composite photocatalyst (PBC-g-C3N4(0.15)) was synthesized for the degradation of pesticides (imidacloprid (IMI), atrazine (ATR), azoxystrobin (AZO)) and antibiotics (tetracycline (TC), ofloxacin (OFX), sulfadiazine (SDZ)) under visible light. PBC-g-C3N4(0.15) achieved 89.7% degradation efficiency for IMI within 120 min, 1.8 times higher than g-C3N4, mainly due to 4.4 times increase in photocurrent density. Active species identified mainly included 1O2, center dot O2-, and center dot OH. Density functional theory and UHPLC-Q Exactive MS analysis suggested three degradation pathways for IMI, with most intermediates predicted to be less toxic than the parent compound. Additionally, PBC-g-C3N4(0.15) was largely unaffected by environmental factors and achieved over 94% degradation efficiencies for AZO, TC, and OFX within 60 min, and over 34% for ATR and SDZ in 120 min. The degradation efficiencies for IMI and TC remained 61.0% and 76.1% after eight cycles, respectively. In natural water, the degradation efficiencies for IMI and TC exceeded 30% and 65%, respectively. This research offers valuable insights into the modification of g-C3N4 and the treatment of pesticides and antibiotics in wastewater.

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