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Identification of Dufulin photolysis and hydrolysis products in water using a 13 C stable isotope assisted HPLC-HRMS strategy

文献类型： 外文期刊

作者： Yu, Bochi 1 ; Man, Yanli 1 ; Sigmund, Gabriel 2 ; Wang, Pingping 1 ; Xie, Jun 1 ; Wang, Wei 1 ; Zhang, Lan 1 ; Mao, Liangang 1 ; Zhu, Lizhen 1 ; Wu, Chi 1 ; Liu, Xingang 1 ;

作者机构： 1.Chinese Acad Agr Sci, Inst Plant Protect, State Key Lab Biol Plant Dis & Insect Pests, Beijing 100193, Peoples R China

2.Wageningen Univ, Environm Technol, POB 17, NL-6700 AA Wageningen, Netherlands

关键词： Dufulin; Stable isotope; Photolysis; Hydrolysis; Transformation products; ECOSAR

期刊名称：WATER RESEARCH （ 影响因子：12.4； 五年影响因子：12.9 ）

ISSN： 0043-1354

年卷期： 2025 年 274 卷

页码：

收录情况： SCI

摘要： Dufulin is an efficient antiviral agent for plants, however, data on its environmental fate, particularly concerning its transformation products (TPs), remain scarce. The TPs formed during abiotic degradation may pose significant environmental risks due to potential toxicity. Therefore, this study systematically investigated the hydrolysis and photolysis kinetics of Dufulin in aqueous solutions across various pH conditions. By employing HPLC-HRMS and 13C stable isotope labeling, we identified and quantified Dufulin and its degradation products. The results indicated that Dufulin undergoes accelerated photolysis under both acidic and alkaline conditions, while hydrolysis, although less influenced by pH, was comparatively slower than photolysis. Six TPs were identified and confirmed, five of which were reported for the first time. Moreover, abiotic transformation pathways of Dufulin in water were proposed. Predictions by the ECOSAR software indicated that the toxicity of two of the identified TPs was higher than that of the parent compound, meriting further assessment. These findings provide crucial insights into the environmental risks associated with Dufulin and underscore the scientific validity of using HPLC-HRMS combined with 13 C stable isotope labeling for TP identification.

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