A novel bis-coumarin gelator W for the selective detection of Al3+and its biological application
文献类型： 外文期刊
作者： Zhang, Ying-Peng 1 ; Liang, Yu-Ning 1 ; Yang, Chen 1 ; Yang, Yun-Shang 1 ; Guo, Hui-Chen 3 ; Zhang, Hong-Rui 5 ;
作者机构： 1.Lanzhou Univ Technol, Sch Petrochem Engn, Lanzhou 730050, Peoples R China
2.Lanzhou Univ Technol, Key Lab Low Carbon Energy & Chem Engn Gansu, Lanzhou 730050, Peoples R China
3.Chinese Acad Agr Sci, State Key Lab Vet Etiol Biol, Lanzhou 730046, Peoples R China
4.Chinese Acad Agr Sci, Lanzhou Vet Res Inst, Key Lab Anim Virol, Minist Agr, Lanzhou 730046, Peoples R China
5.Lanzhou Univ, Sch Pharm, Lanzhou 730000, Peoples R China
关键词： Bis-coumarin; Organic gels; Aluminum ions; Self-assembly
期刊名称：JOURNAL OF MOLECULAR LIQUIDS （ 影响因子：6.0； 五年影响因子：5.6 ）
ISSN： 0167-7322
年卷期： 2024 年 397 卷
页码：
收录情况： SCI
摘要： A novel bis-coumarin gelator W was designed and synthesized. The W has good gel behavior in ethanol, tertbutanol, and isopropanol solutions. The self-assembly mechanism of the W was investigated using techniques such as UV-Vis absorption spectroscopy, infrared spectroscopy, and XRD. The results show that the driving forces for gelation are: 7C -7C stacking, hydrogen bonding, and van der Waals forces, respectively. The effect of solvent on the gelation behavior is analyzed in the Teas plot, which shows that the solvent and the W can only form gels under the appropriate force. Through the optical performance test, the W can specifically recognize Al3+. The detection limit is as low as 7.32 x 10-7 M, the complexation constant is Ka = 1.033 x 103M-1. In addition, the cytotoxicity test of the two cell lines shows that their toxicity is low, which indicates that the W can be used in the field of bioengineering.
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