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Synthesis and Fungicidal Activities of Biaryl Methanone O-Benzyl Oximes

文献类型： 外文期刊

作者： Li Xiuyun 1 ; Wan Chuan 1 ; Du Shijie 1 ; Li Hong 1 ; Yuan Huizhu 2 ; Jiang Jiazhen 1 ; Xiao Yumei 1 ; Qin Zhaohai 1 ;

作者机构： 1.China Agr Univ, Coll Sci, Beijing 100193, Peoples R China

2.Chinese Acad Agr Sci, Inst Plant Protect, Beijing 100193, Peoples R China

关键词： Methoxy acrylate;Pyridinyl phenyl metnanone oxime;Benzyl ether;Fungicidal activity

期刊名称：CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE （ 影响因子：0.65； 五年影响因子：0.481 ）

ISSN： 0251-0790

年卷期： 2015 年 36 卷 12 期

页码：

收录情况： SCI

摘要： To discover new strobilurin analogs with high pesticidal activity, 11 novel methoxy acrylates bearing biaryl methanone oxime ether moieties were synthesized from aroyl pyridines, and characterized by H-1 and C-13 NMR and HRMS. In vitro fungicidal evaluation indicated that all of the target compounds exhibited excellent activities against tested seven phytopathogenic fungi, and compounds 5d and 5g displayed comparable overall activities to azoxystrobin and trifloxystrobin. Some of the target compounds also exhibited excellent in vivo control effects at 400 mg/L, for example, compound 5h could 100% control wheat powdery mildew and cucumber anthracnose. Furthermore, at 25 mg/L, these compounds, including control agents, completely inhibited spores germination of rice blast, but no effect at all for cucumber gray mold. These results suggested that this class of compounds might deserve to be developed as new potential agricultural fungicides.

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