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Determination of Polycyclic Aromatic Hydrocarbons and Halogenated Polycyclic Aromatic Hydrocarbons in Vegetable by Gas Chromatography-Tandem Mass Spectrometry

文献类型: 外文期刊

作者: Wang Li 1 ; Jin Fen 2 ; Li Min-Jie 2 ; Liu Yue; Jiao Bi-Ning 1 ; Shao Hua 2 ; Jin Mao-Jun 2 ; Wang Jing 2 ;

作者机构: 1.Southwest Univ, Coll Food Sci, Chongqing 400715, Peoples R China

2.Chinese Acad Agr Sci, Inst Qual Stand & Testing Technol Agroprod, Key Lab Agroprod Qual & Safety, Beijing 100081, Peoples R China

3.Chinese Acad Agr Sci, Citrus Res Inst, Chongqing 400712, Peoples R China

4.Chinese Acad Agr Sci, Citrus Res

关键词: Polycyclic aromatic hydrocarbons;Halogenated polycyclic aromatic hydrocarbons;Gas chromatography tandem mass spectrometry;Dispersive solid phase extraction;Vegetables

期刊名称:CHINESE JOURNAL OF ANALYTICAL CHEMISTRY ( 影响因子:1.134; 五年影响因子:0.909 )

ISSN: 0253-3820

年卷期: 2013 年 41 卷 6 期

页码:

收录情况: SCI

摘要: A method was developed for determination of 16 polycyclic aromatic hydrocarbons and 11 halogenated polycyclic aromatic hydrocarbons in vegetables by gas chromatography. tandem mass spectrometry(GC-MS/MS). The analytes were extracted from the vegetable samples by hexane, and purified by dispersion solid phase extraction using PSA and C-18 sorbent, then analyzed by gas chromatography. tandem mass spectrometry (GC-MS/MS) with external standard method. The recoveries were in the range of 74. 7% -115. 1%, and the relative standard deviations (RSD) were 1. 6% -15. 3% at three spiked levels of 50,100 and 200 mu g/kg for 16 polycyclic aromatic hydrocarbons and 11 halogenated polycyclic aromatic hydrocarbons. The limits of quantification (LOQ) for all analytes were 0. 03-7. 39 mu g/kg.

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