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Morphology Control of Electrospun Brominated Butyl Rubber Microfibrous Membrane

文献类型: 外文期刊

作者: Zhu, Tianxiao 1 ; Tian, Ruizhi 1 ; Wu, Liang 2 ; Zhang, Dingyi 1 ; Chen, Leying 1 ; Zhang, Xianmei 3 ; Hao, Xiangyang 1 ; Hu, Ping 4 ;

作者机构: 1.China Univ Geosci, Sch Mat Sci & Technol, Engn Res Ctr, Minist Educ Geol Carbon Storage & Low Carbon Utili, Beijing 100083, Peoples R China

2.Peking Univ, Sch Elect, Beijing 100871, Peoples R China

3.Chinese Acad Agr Sci, Inst Agr Resources & Reg Planning, Key Lab Arable Land Qual Monitoring & Evaluat, Minist Agr & Rural Affairs, Beijing 100081, Peoples R China

4.Tsinghua Univ, Dept Chem Engn, Beijing 100084, Peoples R China

关键词: electrospinning; electrospun nanofibers; brominated butyl rubber; anti-bacterial property; conductivity

期刊名称:POLYMERS ( 影响因子:5.0; 五年影响因子:5.0 )

ISSN:

年卷期: 2023 年 15 卷 19 期

页码:

收录情况: SCI

摘要: Brominated butyl rubber (BIIR) is a derivative of butyl rubber, with the advantage of high physical strength, good vibration damping performance, low permeability, aging resistance, weather resistance, etc. However, it is hard to avoid BIIR fiber sticking together due to serious swelling or merging, resulting in few studies on BIIR electrospinning. In this work, brominated butyl rubber membrane (mat) with BIIR microfiber has been prepared by electrospinning. The spinnability of elastomer BIIR has been explored. The factors influencing the morphology of BIIR microfiber membranes have been studied, including solvent, electrospinning parameters, concentration, and the rheological property of electrospinning solution. The optimal parameters for electrospinning BIIR have been obtained. A BIIR membrane with the ideal microfiber morphology has been obtained, which can be peeled from aluminum foil on a collector easily without being broken. Anti-bacterial property, the electrical conductivity of these membranes, and the mechanical properties of these samples were studied. The optimized BIIR electrospinning solution is Bingham fluid. The results of these experiments show that a BIIR membrane can be used in the field of medical prevention, wearable electronics, electronic skin, and in other fields that require antibacterial functional polymer materials.

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