Highly selective histamine assay via SERS: Based on the signal enhancement of carbon dots and the fluorescence quenching of gold nanoparticles
文献类型: 外文期刊
作者: Yang, Dezhi 1 ; Li, Hong 1 ; Li, Qiulan 1 ; Li, Kexiang 1 ; Xiao, Feijian 1 ; Yang, Yaling 1 ;
作者机构: 1.Kunming Univ Sci & Technol, Fac Life Sci & Technol, Kunming 650500, Yunnan, Peoples R China
2.Yunnan Acad Agr Sci, Inst Agroprod Proc, Kunming 650032, Yunnan, Peoples R China
3.Yunnan Lunyang Technol Co Ltd, Kunming 650032, Yunnan, Peoples R China
关键词: Histamine; Surface-enhanced Raman scattering; N,Zn-CDs/beta-CD; Fluorescence interference; Detection
期刊名称:SENSORS AND ACTUATORS B-CHEMICAL ( 影响因子:9.221; 五年影响因子:7.676 )
ISSN:
年卷期: 2022 年 350 卷
页码:
收录情况: SCI
摘要: Fluorescent background is a major obstacle in surface-enhanced Raman scattering (SERS) and limits its application in various fields of science. This research developed a novel strategy by combining the advantages of the carbon dots (CDs) and gold nanoparticles (AuNPs) to increase the SERS signal for histamine (His) detection. The beta-cyclodextrin (beta-CD) decorated N,Zn co-doped carbon dots (N,Zn-CDs/beta-CD) was prepared, which has both highly selective fluorescence (FL) sensitization and selective Raman signal enhancement for His derivatives (D-His). The prepared AuNPs not only could be used to enhance SERS signal, but also could quench 76% of the FL background at 544 nm, which is conducive to suppress the FL interference caused by carbon dots. Interestingly, the SERS signal increased with the gradual quenching of FL through the energy transfer between the fluomphore and the AuNPs. The combination of AuNPs and N,Zn-CDs/beta-CD shows a detection limit of His around 10 mu M, and a selectivity and anti-interference capability for His detection in the present of metal ions, sugar and other biogenic amines. This work exhibits the potential for anti-interference, sensitive and selective detection of His in practical SERS applications.
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