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New insight into the co-removal of arsenic and cadmium from wastewater by using thiol-functionalized UiO-66: A mechanistic study and real water test

文献类型： 外文期刊

作者： Chen, Xinyi 1 ; Li, Lijuan 1 ; Zeng, Lingzhen 3 ; Wang, Yu 2 ; Zhang, Tuo 2 ;

作者机构： 1.Chinese Acad Agr Sci, Inst Agr Environm & Sustainable Dev, Beijing 100081, Peoples R China

2.China West Normal Univ, Coll Environm Sci & Engn, Nanchong 637009, Peoples R China

3.Peking Univ, Coll Chem & Mol Engn, Natl Lab Mol Sci, Beijing 100190, Peoples R China

4.Nanning Normal Univ, Sch Environm & Life Sci, Nanning 530100, Peoples R China

关键词： Cd(II); UiO-66-SH; Co-removal; Wastewater

期刊名称：SEPARATION AND PURIFICATION TECHNOLOGY （ 影响因子：8.6； 五年影响因子：7.8 ）

ISSN： 1383-5866

年卷期： 2024 年 332 卷

页码：

收录情况： SCI

摘要： Industrial wastewater is normally a complex matrix, and few reported MOFs have considered the co-removal of anion and cation contaminants from wastewater. In this study, we synthesized a highly stable thiolfunctionalized MOF (UiO-66-SH) to achieve the coadsorption of As(V) and Cd(II) in an aqueous solution. The morphology, functional groups and thermal properties of UiO-66-SH were examined. The prepared UiO-66-SH possessed an octahedral structure (size: 0.8-2 mu m) with a large surface area (224 m2/g). TEM-EDX mapping showed a uniform distribution of S and Zr throughout UiO-66-SH. The FT-IR spectra showed peaks for -SH at 2566 cm-1, indicating that -SH was successfully incorporated into UiO-66. Adsorption batch experiments showed that both As(V) and Cd(II) were rapidly taken up by UiO-66-SH in the first 6 h, and the removal rates were over 70% and 88%, respectively, after 24 h. The maximum As(V) and Cd(II) adsorption capacities were 52.31 and 77.42 mg/g. The optimum pH values for As(V) and Cd(II) adsorption were 3 and 5, respectively. Except for Pb(II) and phosphate, anions, cations, and humic acid had almost no effect on As(V) and Cd(II) co-removal by UiO-66SH. Spectral analysis indicated that surface hydroxyl groups (Zr-OH) and -SH groups played vital roles in As(V) and Cd(II) adsorption by participating in inner-sphere coordination interactions. A real water test showed that a very small amount of UiO-66-SH could decrease the concentration to below the emission standard within 6 h. Our study demonstrated that UiO-66-SH is a promising adsorbent for treating As- and Cd-cocontaminated mining wastewater, ensuring the environmental safety of wastewater emission.

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