A novel regulable enantioselective platform based on porphyrin tubular cage assemblies with controllable handedness
文献类型： 外文期刊
第一作者： Jiang, Yuying
作者： Jiang, Yuying;Wang, Yutao;Cai, Da;Gao, Rui;Bi, Jingxiu;Liu, Pingxiang;Gao, Lei;Liu, Chao;Wang, Tianyu
作者机构：
关键词： Controllable handedness; Enantioselective platform; Interfacial assembly; Porphyrin tubular cage
期刊名称：COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS （ 影响因子：5.2； 五年影响因子：4.7 ）
ISSN： 0927-7757
年卷期： 2023 年 658 卷
页码：
收录情况： SCI
摘要： Here, the first mono-molecule-diameter sized assembling film with controllable handedness is constructed upon air/water interfacial assembly of porphyrin tubular cage (PTC) with C60 fullerene. The assembling film can be a smart chiral sensing platform for electrochemical recognition of tryptophan (Trp) isomers. Resulting from the non-covalent interactions induced changeable handedness, the discriminating effect of L-and D-Trp is dependent on the chirality of assemblies. This work provides a new idea for developing regulable enantioselective platform.
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