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Photochemistry of Fe(III)-Tetracycline Complexes in Aqueous Solution under UV Irradiation

文献类型: 会议论文

第一作者: Danna Zhou

作者: Danna Zhou 1 ; Jie Wang 2 ; Liwei Hou 2 ; Jing Xu 2 ; Yan Zhao 2 ;

作者机构: 1.Faculty of Material Science and Chemistry, China University of Geosciences

2.School of Resources and Environmental Science, Hubei Key Laboratory of Biomass-Resources Chemistry and Environmental Biotechnology, Wuhan University

关键词: Iron (III);Tetracycline;Photochemistry;Quantum Yields;Iron (II)

会议名称: International Conference on Digital Manufacturing & Automation

主办单位:

页码: 608-611

摘要: The form and photochemistry of the Fe(III)-Tetracycline complex (Fe(III)-TC) in aqueous solution were investigated under UV-C light (254 nm) by UV-Vis spectrometry. The ratio of Fe(III) to Tetracycline (TC) in the Fe(III)-TC complex was 1: 2, as determined by Job's method at a characteristic absorption wavelength of 440 nm. The concentration of Fe(II) produced by the photoreduction of Fe(III) species and the quantum yield of Fe(II) (Φ_(Fe(II))) were determined. The photoreactivity of the Fe(III)-TC complex was higher than that of the Fe(III)-OH complex in terms of Φ_(Fe(II)). The photochemical production of Fe(II) decreased with increasing pH in the range 3.0-9.0.

分类号: tp2-53

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