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A rapid and solid sampling colorimetric sensor of Hg in food based on thermo-release coupled with Au nanozyme trap

文献类型: 外文期刊

作者: Chai, Weiwei 1 ; Liu, Tengpeng 1 ; Huang, Xudong 1 ; He, Qianli 1 ; Li, Xue 1 ; Liu, Jixin 1 ; Mao, Xuefei 1 ;

作者机构: 1.Chinese Acad Agr Sci, Inst Qual Stand & Testing Technol Agroprod, Beijing 100081, Peoples R China

2.Minist Agr & Rural Affairs, Key Lab Agrofood Safety & Qual, Beijing 100081, Peoples R China

3.Beijing Abil Technol Co Ltd, Beijing 100081, Peoples R China

4.Henan Univ Technol, Coll Biol Engn, Zhengzhou 450001, Peoples R China

关键词: Solid sampling colorimetry; Nanozyme-based colorimetry; Gas phase enrichment; Au nanozymes; Mercury; Food

期刊名称:FOOD CONTROL ( 影响因子:6.3; 五年影响因子:6.1 )

ISSN: 0956-7135

年卷期: 2025 年 169 卷

页码:

收录情况: SCI

摘要: Considering complicated matrices, solid sampling analysis of heavy metals in food is almost impossible for ionic nanocolorimetric methods. Here, a novel approach is proposed to fulfill Hg analysis in solid sample based on Au nanozyme colorimetry following thermo-release (TR) and gas phase enrichment (GPE). Gold nanozyme was synthesized to both enable Hg trapping and nanozyme reaction. Furthermore, the presence of Hg-0 enhances the POD activity of Au nanozymes and thereby oxidizes TMB under H2O2, resulting in color change to blue. The method LOD370 for Hg reached 6 mu g/kg in 200 mg rice sample with a good linearity (R-2 > 0.995); the analysis time was less than 25 min excluding digestion or extraction. Mg2+, Fe3+, and Cr- interference was effectively eliminated via thermo-release, GPE and AuNPs amalgamation. It was for the first time rapid and colorimetric detection of Hg in solid sample was achieved for nanozyme, holding a great potential for visualized elemental detection in food.

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