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An asymmetric membrane of polyimide 6FDA-BDAF and its pervaporation desulfurization for n-heptane/thiophene mixtures

文献类型: 外文期刊

作者: Yang Xiang-dong 1 ; Ye Hong 2 ; Li Yan-ting 1 ; Li Juan 1 ; Li Ji-ding 2 ; Zhao Bing-qiang 1 ; Lin Yang-zheng 2 ;

作者机构: 1.Chinese Acad Agr Sci, Inst Agr Resources & Reg Planning, Beijing 100081, Peoples R China

2.Tsinghua Univ, Dept Chem Engn, Beijing 100084, Peoples R China

3.Beijing Technol & Business Univ, Sch Food & Chem Engn, Beijing 100048, Peoples R China

4.Carnegie Inst Sci, Geophys Lab, Washington, DC 20015 USA

关键词: pervaporation;membrane material;fertilizer;desulfurization;n-heptane/thiophene

期刊名称:JOURNAL OF INTEGRATIVE AGRICULTURE ( 影响因子:2.848; 五年影响因子:2.979 )

ISSN: 2095-3119

年卷期: 2015 年 14 卷 12 期

页码:

收录情况: SCI

摘要: Polyimide (PI) is a type of important membrane material. A soluble polymer was synthesized from 4,4 ''-(hexafluoroisopropylidene) diphthalic anhydride (6FDA) and 2,2-bis[4-(4-anninophenoxy) phenyl] hexafluoropropane (BDAF) by the two-step polymerization method. The polymer was proved to be polyimide 6FDA-BDAF by the Fourier transform infrared (FT-IR), the 1H-NMR and 19F-NMR spectra. An asymmetric membrane was prepared with the synthesized polyimide 6FDA-BDAF, it was porous in the 50 pm height bulk and dense in a 3-5 pm height surface. The membrane was used to separate n-heptane/thiophene mixtures by pervaporation with sulfur (S) contents from 50 to 900 pg g(-1). The total flux was enlarged from 7.96 to 37.61 kg m(-2) h(-1) with temperature increasing from 50 to 90 C. The membrane's enrichments factor for thiophene were about 3.13 and dependent on the experimental conditions. The experimental results demonstrated that polyinnide 6FDA-BDAF would be a potential membrane material for desulfurization and controlled release of the S-containing fertilizer.

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