CO2 -responsive deep eutectic solvents for the enhanced extraction of hesperidin from Fertile orange peel
文献类型: 外文期刊
作者: Wang, Shanshan 1 ; Lei, Tian 2 ; Liu, Leilei 1 ; Tan, Zhijian 3 ;
作者机构: 1.Jishou Univ, Key Lab Hunan Forest Prod & Chem Ind Engn, Natl & Local United Engn Lab Integrat Utilizat Euc, Zhangjiajie 427000, Peoples R China
2.Jishou Univ, Coll Chem & Chem Engn, Jishou 416000, Peoples R China
3.Chinese Acad Agr Sci, Inst Bast Fiber Crops, Changsha 410205, Peoples R China
4.Chinese Acad Agr Sci, Ctr Southern Econ Crops, Changsha 410205, Peoples R China
关键词: CO 2-responsive deep eutectic solvents; Recyclable extractants; Extraction; Bioactive compounds; Hesperidin
期刊名称:FOOD CHEMISTRY ( 影响因子:8.8; 五年影响因子:8.6 )
ISSN: 0308-8146
年卷期: 2024 年 432 卷
页码:
收录情况: SCI
摘要: Hesperidin, also known as vitamin P, is widely studied for its distinctive potential in food and pharmaceutical industries. This work focuses on the research of CO2-responsive deep eutectic solvents (DESs) used as recyclable extractants for efficient extraction of hesperidin from Fertile orange peel. Reversible phase transformation of DES solution was achieved by bubbling CO2/N2. The maximum extraction yield of 22.39 mg/g was obtained for hesperidin under the following conditions: DES-6 (triethanolamine: 4-methoxyphenol = 1:1) used as extractant, water content of 35 wt%, solid-liquid ratio of 1:60 g/mL, extraction temperature of 25 degrees C, and ultrasonic time of 25 min, which was much higher than that extracted by methanol. Hesperidin of 74.38% was recovered in top phase after CO2 triggering. Density function theory (DFT) results indicated that hydrogen and & pi;-& pi; bonds were the main factors affecting hesperidin extraction. This study provides a new idea for extracting natural bioactive compounds using recyclable extractants.
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