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Organic contaminants removal and carbon sequestration using pig manure solid residue-derived biochar: A novel closed-loop strategy for anaerobic liquid digestate

文献类型： 外文期刊

作者： Liu, Ziyun 1 ; Xie, Shihao 2 ; Zhou, Hongxu 4 ; Zhao, Lixin 1 ; Yao, Zonglu 1 ; Fan, Honggang 2 ; Si, Buchun 3 ; Yang, Gaixiu 2 ;

作者机构： 1.CAAS, Minist Agr & Rural Affairs PR China, Inst Environm & Sustainable Dev Agr, Key Lab Low carbon Green Agr North China, Beijing 100081, Peoples R China

2.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China

3.China Agr Univ, Coll Water Resources & Civil Engn, Key Lab Agr Engn Struct & Environm, Minist Agr & Rural Affairs, Beijing 100083, Peoples R China

4.Univ Illinois, Dept Agr & Biol Engn, Urbana, IL 61801 USA

5.Univ Illinois, Illinois Sustainable Technol Ctr, Champaign, IL 61820 USA

关键词： Solid digestate-derived biochar; Anaerobic liquid digestate; Organic pollutants; Carbon sequestration; Adsorption

期刊名称：CHEMICAL ENGINEERING JOURNAL （ 影响因子：15.1； 五年影响因子：14.3 ）

ISSN： 1385-8947

年卷期： 2023 年 471 卷

页码：

收录情况： SCI

摘要： Anaerobic digestion of livestock manure as a carbon-negative practice yields bioenergy and biofertilizer. However, substantial antibiotics and benzenes contained in liquid and solid digestate hinder its large-scale applications. In this study, a novel closed-loop treatment strategy was proposed to integrate the synthesis benefits of anaerobic digestion, pyrolysis of solid digestate, and adsorption. The solid digestate-derived biochar (S-biochar) was successfully prepared by coupling pyrolysis and H2SO4 activation. The S-biochar possessed a polycyclic aromatic structure, abundant micropores (0.8-1.0 nm), various functional groups (-COOH, Aro-OH), and a higher absolute zeta potential value. These characteristics contributed to the excellent adsorption of tetracycline (51.3 mg/L), oxytetracycline (32.9 mg/L), benzene (86.0 mg/L) and toluene (74.1 mg/L), wherein pore filling, electrostatic interactions, H-bonding, surface partition, and 7c-7c conjugation mechanisms were involved. The adsorption of antibiotics was more sensitive to pH, in comparison with benzenes, and displayed a declining trend (pH>7). Under actual liquid digestate conditions, >95% adsorption of antibiotics and benzenes were reached at the dosage of 1.5 g/L, in a company with >80% of nitrogen and phosphorus. In the end, a carbon and nitrogen flow analysis was performed to elucidate that more than 80% of carbon in pig manure can be settled as biochar and biogas, and up to 94.7% of nitrogen remained in the biochar and liquid digestate. This study not only developed a S-biochar with excellent performance in removing organic pollutants from liquid digestate, but also established a closed-loop strategy as an alternative carbon sequestration approach using anaerobic digestion side-products.

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