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Chloride-enhanced degradation of micropollutants in natural water by the iron/biochar/peroxymonosulfate system: Role of iron(IV) and radicals

文献类型： 外文期刊

作者： Zhang, Mengqiao 1 ; Gong, Wenwen 2 ; Wang, Xiling 1 ; Blaney, Lee 3 ; Peng, Guilong 1 ; Sharma, Virender K. 4 ;

作者机构： 1.Southwest Univ, Coll Sericulture Text & Biomass Sci, State Key Lab Resource Insects, Chongqing 400715, Peoples R China

2.Beijing Acad Agr & Forestry Sci, Inst Qual Stand & Testing Technol, Beijing 100097, Peoples R China

3.Univ Maryland Baltimore Cty, Dept Chem Biochem & Environm Engn, Baltimore, MD 21250 USA

4.Univ Miami, Dept Chem Environm & Mat Engn, 1251 Mem Dr, Miami, FL 33146 USA

关键词： Iron(IV); Biochar; Oxidation; Ferrate; Reactive chlorine species

期刊名称：JOURNAL OF HAZARDOUS MATERIALS （ 影响因子：11.3； 五年影响因子：12.4 ）

ISSN： 0304-3894

年卷期： 2025 年 492 卷

页码：

收录情况： SCI

摘要： The increased occurrence and concentration of micropollutants in water supplies raise public health concerns. Advanced oxidation of micropollutants in real water sources remains challenging due to scavenging reactions involving background anions and natural organic matter. For the first time, this paper demonstrates that chloride (Cl-) accelerates the activation of peroxymonosulfate (PMS) by iron-biochar (Fe/BC) composites. Under the tested conditions, this novel system completely degraded bisphenol A (BPA), a representative micropollutant, within 1.0 min. Micropollutant degradation was investigated at different Cl-contents, PMS levels, Fe/BC doses, and solution pH. The primary reactive species involved with BPA degradation were iron(IV) (Fe(IV)), sulfate radical (SO4 center dot-), hydroxyl radical (center dot OH), and reactive chlorine species (Cl center dot, ClO center dot, Cl2 center dot-). The steady-state concentrations of these reactive species were evaluated to determine their relationships to the Cl-and PMS contents. Fe (IV) was confirmed as the dominant reactive species, with Fe(IV) concentrations increasing with Cl-content and salinity to enhance the overall BPA degradation. Importantly, BPA degradation by the Fe/BC/PMS/Cl-system was not greatly affected by background anions or natural organic matter (NOM) present in real water sources, and the system was successfully applied for five sequential cycles of BPA treatment.

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