Dissipation, residue, dietary, and ecological risk assessment of atrazine in apples, grapes, tea, and their soil
文献类型: 外文期刊
作者: Yuan, Longfei 1 ; Chai, Yida 1 ; Li, Congdi 1 ; Liu, Rong 3 ; Chen, Zenglong 1 ; Li, Li 1 ; Li, Wei 1 ; He, Yujian 2 ;
作者机构: 1.Chinese Acad Sci, Inst Zool, State Key Lab Integrated Management Pest Insects, Beijing 100101, Peoples R China
2.Univ Chinese Acad Sci, Sch Future Technol, Beijing 101408, Peoples R China
3.Chinese Acad Agr Sci, Inst Crop Sci, Beijing 100081, Peoples R China
4.Yangtze Univ, Sch Agr, Jingzhou 434025, Peoples R China
关键词: Atrazine; Dissipation; Residue; Dietary risk assessment; Ecological risk assessment
期刊名称:ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH ( 影响因子:4.223; 五年影响因子:4.306 )
ISSN: 0944-1344
年卷期:
页码:
收录情况: SCI
摘要: Atrazine is one of the most used herbicides in China. It is a persistent organic pollutant but has been widely used on Chinese farmlands for a long time. To assess its dietary and ecological risks to human and environment, in this study, atrazine residues were extracted with acetonitrile and then plant samples were detected with gas chromatography coupled with mass spectrometry (GC-MS) and soil samples were determined with gas chromatography coupled with nitrogen-phosphorus detector (GC-NPD). The limit of quantification (LOQ) of the method was 0.01 mg/kg for all matrices. The recoveries ranged from 82.0 to 105.4% for plant samples and 75.6 to 85.6% for soil samples. The final residues of atrazine in all plant samples were lower than LOQ. Dietary risk assessment suggested that under good agricultural practices (GAP) conditions, intake of atrazine from apples, grapes, and tea would exhibit an acceptably low health risk on consumers. However, the final residues of atrazine in soil samples were <0.01-9.2 mg/kg, and the half-lives were 2.0-9.1 days. Based on the species sensitivity distribution (SSD) model, the potential affected fraction (PAF) of atrazine in soil samples ranges from 0.01 to 65.8%. Atrazine residues in 43.1% soil samples were higher than 0.11 mg/kg, which was the hazardous concentration for 5% of species (HC5) of atrazine in soil. These results suggested that the ecological risks of atrazine in apples, grapes, and tea garden soil would exhibit a high risk on environmental species even under the same GAP conditions. This study could provide guidance for comprehensive risk assessment of atrazine properly used in apple, grape, and tea gardens.
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